From: "Saved by Windows Internet Explorer 7" Subject: Haz-Map: Occupational Exposure to Hazardous Agents Date: Fri, 17 Aug 2007 07:46:46 -0700 MIME-Version: 1.0 Content-Type: multipart/related; type="text/html"; boundary="----=_NextPart_000_0000_01C7E0A2.C33F2E50" X-MimeOLE: Produced By Microsoft MimeOLE V6.0.6000.16480 This is a multi-part message in MIME format. ------=_NextPart_000_0000_01C7E0A2.C33F2E50 Content-Type: text/html; charset="iso-8859-1" Content-Transfer-Encoding: quoted-printable Content-Location: http://hazmap.nlm.nih.gov/cgi-bin/hazmap_generic?tbl=TblAgents&id=1148 Haz-Map: Occupational Exposure to Hazardous = Agents
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Agent Name Chromic acid and = chromates
CAS=20 Number 7738-94-5, varies
Formula Cr-O3, varies
Major = Category Metals
Synonyms Chromic acid (CrO3): Chromic = anhydride,=20 Chromic oxide, Chromium(VI) oxide (1:3), Chromium = trioxide;=20 Synonyms of chromates (i.e., chromium(VI) compounds) = such as=20 zinc chromate vary depending upon the specific = compound.
Category Metals, Inorganic = Compounds
Description CrO3: Dark-red, odorless flakes or = powder.=20 [Note: Often used in an aqueous solution = (H2CrO4)]
Sources/Uses Used in electroplating, metal = cleaning,=20 leather tanning, and photography; [HSDB]
Comments Classified as a water-soluble, = hexavalent=20 chromium compound; [ACGIH] Chronic exposure to = hexavalent=20 chromium may produce evidence of kidney and liver = injury.=20 [ATSDR Case Studies # 4] Can cause second and third = degree=20 burns on short contact; [CHRIS] Highly corrosive to = skin;=20 [Quick CPC] Occupational asthma documented in a cement = floor=20 worker, plater, and other workers exposed to chromate = salt;=20 [Malo] See "Chromium."
Exposure=20 Assessment
Skin = Designation (ACGIH) No
Bioacc= umulates Yes
TLV=20 (ACGIH) 0.05 mg/m3, as Cr
PEL=20 (OSHA) Ceiling(OSHA) =3D 0.1 mg/m3, as = CrO3
IDLH=20 (NIOSH) 15 mg/m3, as Cr(VI)
Excerpts from Documentation=20 for IDLHs Human data: A worker exposed for = several=20 days to concentrations of chromic acid mist of about = 20 to 30=20 mg/m3 (equivalent to about 10 to 15 mg Cr(VI)/m3) = experienced=20 cough, headache, dyspnea, and substernal pain; the = signs=20 persisted for 2 weeks [ILO 1971]. Another man working = on the=20 same process was similarly but less severely affected = [ILO=20 1971].
Explanatory = Notes The hyperlink to the Emergency = Response=20 Guidebook is for "chromic acid, solution."
Reference = Link International=20 Chemical Safety Cards (WHO/IPCS/ILO)
Flammabil= ity=20 (NFPA) 0:=20 will not burn
Adverse=20 Effects
AsthmaYes
Lung Cancer Yes
Dermatoto= xin Skin Burns
Skin=20 Sensitizer Yes
Hepatotoxi= n Hepatotoxin, Secondary
Nephrotoxi= n Yes
Rep= roductive=20 Toxin Yes
IARC=20 Carcinogen Known Carcinogen
Links to Other=20 NLM Databases
Health Studies Human Health Effects from Hazardous = Substances Data Bank: CHROMIUM=20 COMPOUNDS  
Toxicity Information Search=20 TOXNET
Chemical Information Search=20 ChemIDplus
Biomedical References Search=20 PubMed
Related=20 Information in Haz-Map
Diseases Diseases associated = with=20 exposure to this agent:=20
  • Asthma,=20 occupational=20
  • Chromium,=20 chronic toxic effect=20
  • Contact=20 dermatitis, allergic=20
  • Lung=20 cancer
    Processes Industrial Processes = with risk=20 of exposure:=20
    • Acid=20 and Alkali Cleaning of Metals=20
    • Electroplating=20
    • Photographic=20 Processing=20
    • Tanning=20 Leather
    =





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      =   U.S. National Library of = Medicine,
      8600=20 Rockville Pike, Bethesda, MD 20894
      National=20 Institutes of Health
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      Last = updated:=20 July, 2007
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