From: "Saved by Windows Internet Explorer 8" Subject: CHROMIUM(VI) OXIDE (ICSC) Date: Sun, 27 Feb 2011 04:09:27 -0800 MIME-Version: 1.0 Content-Type: multipart/related; type="text/html"; boundary="----=_NextPart_000_000F_01CBD634.2016A6F0" X-MimeOLE: Produced By Microsoft MimeOLE V6.0.6002.18263 This is a multi-part message in MIME format. ------=_NextPart_000_000F_01CBD634.2016A6F0 Content-Type: text/html; charset="Windows-1252" Content-Transfer-Encoding: quoted-printable Content-Location: http://www.inchem.org/documents/icsc/icsc/eics1194.htm CHROMIUM(VI) OXIDE (ICSC)
3D"IPCS
CHROMIUM(VI)=20 OXIDE ICSC: 1194
Date of Peer Review: October 2004

Chromic trioxide
Chromic acid
Chromic=20 anhydride
CAS = # 1333-82-0 = CrO3=20
RTECS #=20 GB6650000=20 Molecular mass:=20 100.0
UN = # 1463
EC = # 024-001-00-0=20
TYPES OF HAZARD / EXPOSURE ACUTE HAZARDS / SYMPTOMS PREVENTION FIRST AID / FIRE FIGHTING
FIRE=20 Not=20 combustible but enhances combustion of other substances. Many = reactions=20 may cause fire or explosion.
NO contact=20 with combustible substances and reducing agents.
NO water. In=20 case of fire in the surroundings: use appropriate extinguishing = media.=20
EXPLOSION


EXPOSURE
PREVENT=20 DISPERSION OF DUST! AVOID ALL CONTACT!
IN ALL=20 CASES CONSULT A DOCTOR!
Inhalation Cough.=20 Laboured breathing. Shortness of breath. Sore throat. Wheezing. = Burning=20 sensation. Symptoms may be delayed (see Notes).
Closed=20 system and ventilation.
Fresh air,=20 rest. Half-upright position. Artificial respiration may be needed. = Refer=20 for medical attention.
Skin=20 Redness.=20 Skin burns. Pain.
Protective=20 gloves. Protective clothing.
Remove=20 contaminated clothes. Rinse skin with plenty of water or shower. = Refer for=20 medical attention.
Eyes=20 Redness.=20 Pain. Severe deep burns.
Safety=20 goggles, or eye protection in combination with breathing = protection.=20
First rinse=20 with plenty of water for several minutes (remove contact lenses if = easily=20 possible), then take to a doctor.
Ingestion Abdominal=20 pain. Burning sensation. Shock or collapse.
Do not eat,=20 drink, or smoke during work. Wash hands before eating. =
Rinse mouth.=20 Do NOT induce vomiting. Refer for medical attention.=20
SPILLAGE DISPOSAL PACKAGING & LABELLING
Do NOT let=20 this chemical enter the environment. Vacuum spilled material. OR = Sweep=20 spilled substance into sealable containers; if appropriate, = moisten first=20 to prevent dusting. Carefully collect remainder, then remove to = safe=20 place. Do NOT absorb in saw-dust or other combustible absorbents. = Personal=20 protection: complete protective clothing including self-contained=20 breathing apparatus.
Do not=20 transport with food and feedstuffs.
EU Classification=20
Symbol: O, T+, N
R: 45-46-9-24/25-26-35-42/43-48/23-62-50/53
S: = 53-45-60-61
Note:=20 [E]
UN Classification
UN Hazard Class: 5.1
UN = Subsidiary=20 Risks: 8
UN Pack Group: II
EMERGENCY RESPONSE SAFE=20 STORAGE
Transport=20 Emergency Card: TEC (R)-51S1463
NFPA Code: H3; F0; R1; OX=20
Separated=20 from combustible and reducing substances, bases, food and = feedstuffs. Dry.=20
IPCS =
International
Programme on
Chemical=20 Safety
Prepared in the = context of=20 cooperation between the International Programme on Chemical = Safety=20 and the Commission of the European Communities =A9 IPCS, CEC = 2004=20

SEE IMPORTANT INFORMATION ON BACK=20
CHROMIUM(VI)=20 OXIDE ICSC: 1194=20
IMPORTANT DATA
PHYSICAL=20 STATE; APPEARANCE:
ODOURLESS, DARK RED DELIQUESCENT = CRYSTALS,=20 FLAKES OR GRANULAR POWDER.

CHEMICAL DANGERS:
The = substance decomposes above 250=B0C to chromic oxide and oxygen, = which=20 increases fire hazard. The substance is a strong oxidant and = reacts=20 violently with combustible and reducing materials causing fire and = explosion hazard. The solution in water is a strong acid, it = reacts=20 violently with bases and is corrosive.

OCCUPATIONAL = EXPOSURE=20 LIMITS:
TLV: (as chromium, water-soluble Cr (VI) = compounds) 0.05=20 mg/m=B3 as TWA; A1; BEI issued; (ACGIH 2004).
MAK: Sh; = Carcinogen=20 category: 2; (DFG 2004).
ROUTES OF=20 EXPOSURE:
The substance can be absorbed into the body by=20 inhalation and through the skin and by = ingestion.

INHALATION=20 RISK:
Evaporation at 20=B0C is negligible; a harmful = concentration=20 of airborne particles can, however, be reached quickly when = dispersed,=20 especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:=20
The substance is corrosive to the eyes, the skin and the=20 respiratory tract. Corrosive on ingestion.

EFFECTS OF = LONG-TERM=20 OR REPEATED EXPOSURE:
Repeated or prolonged contact may = cause skin=20 sensitization. Repeated or prolonged inhalation exposure may cause = asthma.=20 The substance may have effects on the respiratory tract, kidneys,=20 resulting in nasal septum perforation, kidney impairment. This = substance=20 is carcinogenic to humans. May cause heritable genetic damage to = human=20 germ cells. Animal tests show that this substance possibly causes = toxicity=20 to human reproduction or development.
PHYSICAL PROPERTIES
Decomposes=20 below boiling point at 250=B0C
Melting point: = 197=B0C
Density: 2.7=20 g/cm=B3
Solubility in water: good
ENVIRONMENTAL DATA
The substance is very toxic to aquatic organisms. It = is=20 strongly advised that this substance does not enter the = environment.=20
NOTES
Rinse contaminated clothes (fire hazard) with plenty = of water.=20 The symptoms of asthma often do not become manifest until a few = hours have=20 passed and they are aggravated by physical effort. Rest and = medical=20 observation are therefore essential. Anyone who has shown symptoms = of=20 asthma due to this substance should avoid all further contact. Do = NOT take=20 working clothes home. Depending on the degree of exposure, = periodic=20 medical examination is suggested.
ADDITIONAL INFORMATION


LEGAL NOTICE Neither the CEC nor the IPCS nor any person = acting on=20 behalf of the CEC or the IPCS is responsible for the use = which might=20 be made of this information =
=A9 IPCS, CEC=20 2004
    See Also:
       Toxic=
ological Abbreviations
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